Photoelectric (PE) absorption of x-rays occurs when the x-ray photon is absorbed, resulting in the ejection of electrons from the outer shell of the atom, and hence the ionization of the atom. Subsequently, the ionized atom returns to the neutral state with the emission of an x-ray characteristic of the atom. This subsequent emission of lower energy photons is generally absorbed and does not contribute to (or hinder) the image making process. Photoelectron absorption is the dominant process for x-ray absorption up to energies of about 500 KeV. Photoelectron absorption is also dominant for atoms of high atomic numbers.
Compton scattering (C) occurs when the incident x-ray photon is deflected from its original path by an interaction with an electron. The electron gains energy and is ejected from its orbital position. The x-ray photon loses energy due to the interaction but continues to travel through the material along an altered path. Since the scattered x-ray photon has less energy, it, therefore, has a longer wavelength than the incident photon. The event is also known as incoherent scattering because the photon energy change resulting from an interaction is not always orderly and consistent. The energy shift depends on the angle of scattering and not on the nature of the scattering medium. Click here for more information on Compton scattering and the relationship between the scatter angle and photon energy.
Pair production (PP) can occur when the x-ray photon energy is greater than 1.02 MeV, but really only becomes significant at energies around 10 MeV. Pair production occurs when an electron and positron are created with the annihilation of the x-ray photon. Positrons are very short lived and disappear (positron annihilation) with the formation of two photons of 0.51 MeV energy. Pair production is of particular importance when high-energy photons pass through materials of a high atomic number
